Superhydrophobic chitosan films via SiO2/PDMS coating for reducing liquid food residue

作者：Mengting Yu, Yujing Sun, Na Ji, Lei Dai, Man Li, Xuyan Dong, Liu Xiong, Qingjie Sun · 发表于：Industrial Crops and Products · 年份：2025 · DOI：10.1016/j.indcrop.2025.122003 · 被引用次数：8 · 研究领域：Surface Modification and Superhydrophobicity、Electrohydrodynamics and Fluid Dynamics、Electrospun Nanofibers in Biomedical Applications

Superhydrophobic coatings have gained significant interest due to their ability to prevent liquid foods like juice and yogurt from adhering to the inner surfaces of containers, thus reducing waste. Superhydrophobic coatings limit its application due to its toxicity, degradability and other reasons. In this work, chitosan sodium phytate films were deposited on glass plates by layer-by-layer self-assembly (LBL), then SiO 2 nanoparticles were introduced to construct micro/nano-structures, and finally, surface modification with polydimethylsiloxane (PDMS) was carried out to prepare superhydrophobic films. The surface of the superhydrophobic film had a micro/nano-scale structure similar to that of lotus leaves. The water contact angle (WCA) of superhydrophobic films reached 153°, and sliding contact angle (SA) was 5°. Owing to this unique structure, different liquid food droplets could roll off freely in a near spherical form on the chitosan phytate film surfaces, effectively reducing residue during container pouring. The outcomes of this study are expected to expand the potential applications of superhydrophobic chitosan films in liquid food anti-adhesion. Schematic diagram of the preparation process of a superhydrophobic chitosan sodium phytate film and its application in the field of reducing liquid residue. • A superhydrophobic film was prepared by SiO 2 nanoparticles and PDMS coating. • The contact angle of the superhydrophobic chitosan film was 153°. • Superhydrophobic films...