Comparative Electrochemical Analysis of Lithium and Lithium-Indium Alloy in All-Solid-State Battery

作者：Se-Jin Park, So-Young Joo, Heon-Cheol Shin · 发表于：ECS Meeting Abstracts · 年份：2024 · DOI：10.1149/ma2024-02674507mtgabs

Lithium-ion batteries (LIBs) are widely used in a variety of applications due to their high energy and power densities, and long cycle life. With the expanding use of LIBs in electric vehicles and energy storage systems, there is very active research into all-solid-state batteries (ASSBs), which offer greater energy density than traditional LIBs and eliminate the inherent fire hazards. Since most of the detailed reactions involved in the performance and degradation of a battery are temperature-sensitive, so-called thermal activation processes, it is very important to accurately assess whether a battery can have the high performance and low degradation characteristics required under different climatic conditions. To evaluate the electrochemical properties of electrode materials in LIBs, a half-cell is typically constructed with the electrode of interest as the working electrode (WE) and lithium metal as auxiliary electrode (AE). Here, lithium metal is close to an ideal non-polarizable material, has a large capacity, and maintains a constant potential during charge/discharge, so it is widely used as AE material in LIB research. However, several issues arise when lithium is used as AE in ASSBs: Lithium metal undergoes mechanical deformation due to the relatively high internal pressure required to ensure good contact between lithium and solid electrolyte; When in contact with sulfide-based solid electrolytes, which are currently of interest due to their high ionic conductivity, s...