25 years of Reticular Chemistry.

作者：R. Freund, S. Canossa, Seth M. Cohen, Wei Yan, Hexiang Deng, Vincent Guillerm, M. Eddaoudi, David G. Madden, David Fairen-jimenez, Hao Lyu, L. Macreadie, Zhe Ji, Yuanyuan Zhang, Bo Wang, Frederik Haase, C. Wöll, Orysia Zaremba, Jacopo Andreo, S. Wuttke, Christian S. Diercks · 发表于：Angewandte Chemie · 年份：2021 · DOI：10.1002/anie.202101644 · 被引用次数：293 · 研究领域：Medicine

At its core, reticular chemistry has translated the precision and expertise of organic and inorganic synthesis to the solid state. While initial excitement over metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) was undoubtedly fueled by their unprecedented porosity and surface areas, the most profound scientific innovation of the field has been the elaboration of design strategies for the synthesis of extended crystalline solids through strong directional bonds. In this contribution we highlight the different classes of reticular materials that have been developed, how these frameworks can be functionalized and how complexity can be introduced into their backbones. Finally, we show how the structural control over these materials is being extended from the molecular scale to their crystal morphology and shape on the nanoscale, all the way to their shaping on the bulk scale.