Chiral Dysprosium Single‐Molecule Magnets Displaying Circular Polarized Luminescence and Magneto‐Chiral Dichroism

作者：Peng‐Xu Lu, Langit Cahya Adi, Pei‐Yu Liao, Wei Deng, Hai‐Ling Wang, Jian-Hua Jia, G. L. J. A. Rikken, Cyrille Train, Matteo Atzori, Ming‐liang Tong · 发表于：Angewandte Chemie International Edition · 年份：2026 · DOI：10.1002/anie.2565905 · 被引用次数：2 · 研究领域：Magnetism in coordination complexes、Synthesis and Properties of Aromatic Compounds、Lanthanide and Transition Metal Complexes

ABSTRACT The combination of single‐molecule magnet (SMM) behavior with chiroptical and magneto‐(chiro)optical properties allows for the preparation of functional materials responsive to light and magnetic fields. Herein, we report on novel enantiopure chiral lanthanide (Ln) SMMs derived from the [Ln(bbpen)] + scaffold (bbpen = N,N′‐bis(2‐hydroxybenzyl)‐N,N′‐bis(2‐methylpyridyl)ethylenediamine), formulated as [Dy(bbpen)((1 S ,2 S )/(1 R ,2 R )‐ chxn )](BPh 4 ) ( Dy‐ S / R ) ( chxn = 1,2‐diaminocyclohexane). These chiral complexes exhibit SMM behavior associated with effective energy barriers over 800 K and strong room‐temperature NCD and MCD responses, as evidenced by the g NCD and g MCD dissymmetry factors. CPL measurements at room temperature reveal | g lum | values of 0.23(2) for the 4 F 9/2 → 6 H 11/2 magnetic dipole‐allowed transition, setting a new record value in the realm of chiral SMMs. Furthermore, variable‐temperature and variable‐field MChD spectroscopy measurements reveal among the strongest magneto‐chiral optical responses reported so far for Dy III chiral complexes, despite the electric‐dipole induced nature of the Dy III f‐f electronic transitions. Dynamic MChD measurement at low temperature allowed us to optically trace the magnetic hysteresis cycles for both enantiomers and for different electronic transitions. Overall, this study establishes the bbpen scaffold as an ideal building block for the preparation of multifunctional materials and open great perspect...