Chemical Control of Supramolecular Copolymerization by Modulating the Chirality Transfer of Helical-Chiral Pillar[5]arenes

作者：De-Hui Tuo, Kazuma Yasuhara, Yuuya Nagata, Moe Ogasawara, Hitoshi Asakawa, Shunsuke Ohtani, Kenichi Kato, Tomoki Ogoshi · 发表于：Journal of the American Chemical Society · 年份：2026 · DOI：10.1021/jacs.5c23106 · 被引用次数：2 · 研究领域：Synthesis and Properties of Aromatic Compounds、Supramolecular Chemistry and Complexes、Supramolecular Self-Assembly in Materials

-helical basic and acidic P5A monomers. The polymerization can be accelerated by acidic or basic additives and suppressed by the addition of guest molecules. Because of the multiple helical-sense-matched ion-pairing interactions, the resulting supramolecular copolymer exhibited exceptional stability in polar solvents, at high temperatures, and in harsh environments.