Carbon tetrafluoride – sulphur hexafluoride adsorption and separation with zirconium metal–organic frameworks decorated with fluorinated thiazolium salts

作者：Giacomo Provinciali, Giulio Bicchierai, Zhi Fang, Tongan Yan, Lorenzo Donà, Bartolomeo Civalleri, Hongliang Huang, Giuliano Giambastiani, Giulia Tuci, Andrea Rossin · 发表于：Journal of Materials Chemistry A · 年份：2026 · DOI：10.1039/d5ta10343f · 被引用次数：2 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Inorganic Fluorides and Related Compounds、Zeolite Catalysis and Synthesis

Fluorinated thiazolium salts embedded in a microporous zirconium MOF enhance its adsorption capacity towards SF 6 and CF 4 . The F-MOFs show a preferential adsorption for SF 6 , achieving an efficient SF 6 /CF 4 separation from binary equimolar mixtures.