Photocatalytic radical (O)P–P(O) bond formation: access to diphosphine dioxides for thermoset protection

作者：Zhicheng Fu, Yu Qin, Hongjun Yang, Wenli An, Ting Wang, Jinni Deng, Ming-Jun Chen · 发表于：Green Chemistry · 年份：2026 · DOI：10.1039/d5gc07067h · 被引用次数：15 · 研究领域：Radical Photochemical Reactions、Phosphorus compounds and reactions、Asymmetric Hydrogenation and Catalysis

A photocatalytic radical coupling method synthesizes diphosphine dioxides in high yields on a kilogram scale and uses recyclable catalysts/solvents via filtration. Moreover, it achieves thermoset protection in extreme environments.