A Golden Fullerene Encapsulating Schmid Gold

作者：Peiyao Pan, Sami Malola, Rui Zhao, Wentao Huang, Emmi Pohjolainen, María Francisca Matus, Meng Zhou, Xi Kang, Hannu Häkkinen, Manzhou Zhu · 发表于：Journal of the American Chemical Society · 年份：2026 · DOI：10.1021/jacs.5c20164 · 被引用次数：8 · 研究领域：Nanocluster Synthesis and Applications、Gold and Silver Nanoparticles Synthesis and Applications、Advanced Chemical Physics Studies

High Resolution Image Download MS PowerPoint Slide Since its first synthesis in 1981, determining the structure of the “Schmid gold”─initially determined as a Au 55 (PPh 3 ) 12 Cl 6 cluster─has remained a big challenge. In this study, fluorine chemistry is exploited to stabilize the largest structurally resolved gold nanocluster stabilized by phosphine ligands, Au 75 (P(C 6 H 4 -4-CF 3 ) 3 ) 20 Cl 12, with which the atomically precise structure of the Schmid gold was optimized. The Au 75 nanocluster displays a Russian doll-like shell-by-shell configuration of Au 13 @Au 42 @Au 20 @Cl 12 @(PR) 20 . The first two shells resemble the metallic core of the Schmid gold, which is encapsulated by an Au 20 shell showcasing a fullerene-like topology. Consequently, the structure of the Au 75 nanocluster is referred to as the “golden fullerene encapsulating Schmid gold”. The geometric constraints of Au 20 @Au 55 dominate over size effects in dictating photodynamics in the Au 75 nanocluster. Density functional theory analysis revealed the superatomic character of the fluorinated Au 75 nanocluster and molecular dynamics simulations up to three microsecond time scale confirmed the role of fluorine chemistry in stabilizing its structure. This study demonstrates the potential to stabilize large phosphine-protected gold nanoclusters by fluorine chemistry opening doors to understanding their functionality in catalysis and biological applications.