Enhancing Ultrahigh-Rate Stability of LiNi 0.5 Mn 1.5 O 4 Cathode Via Interfacial Stabilization and Phase Transition Suppression

作者：Shan Wang, Yilong Jia, Ruida Zhao, Zhuohui Sun, Xiangdong Ding, Youlong Xu · 发表于：ACS Applied Materials & Interfaces · 年份：2025 · DOI：10.1021/acsami.5c18879 · 研究领域：Advancements in Battery Materials、Advanced Battery Materials and Technologies、Advanced Battery Technologies Research

Spinel LiNi 0.5 Mn 1.5 O 4 (LNMO) is a promising high-voltage cathode for low-cost and high-power lithium-ion batteries. However, issues such as interfacial side reactions, Mn dissolution, and two-phase transition during cycling hinder its commercialization by causing structural degradation and capacity fading. Here, we demonstrate a dual-functional modification strategy that simultaneously stabilizes LNMO interface and suppresses the two-phase transition. This is realized by constructing a stable CeO 2 surface layer while incorporating a fraction of Ce into the bulk 16d sites. A series of characterizations confirm that the CeO 2 layer mitigates Mn dissolution and HF corrosion, whereas Ce incorporation into the bulk 16d site stabilizes the lattice structure and facilitates Li + diffusion. As a result, the dual-functional modified LNMO exhibits exceptional ultrahigh-rate performance, delivering 117.8 mAh g –1 at 10 C with 96.1% retention after 500 cycles, far outperforming the pristine material (71.6%). Even after 1000 cycles, 88.8% capacity retention is preserved. This study establishes an effective interfacial stabilization and phase transition suppression strategy for high-voltage cathodes, offering valuable insights into the development of next-generation fast-charging lithium-ion batteries.