Upcycling Polyethylene into Separable Aromatics Through Tandem Catalysis with CO2 at Atmospheric Pressure

作者：Wenjun Chen, Mingyu Chu, Yue Liu, Yiyi Fan, Meiqi Zhang, Meng Wang, Fan Zhang · 发表于：Engineering · 年份：2025 · DOI：10.1016/j.eng.2025.12.006 · 被引用次数：1 · 研究领域：Carbon dioxide utilization in catalysis、Polymer Foaming and Composites、Membrane Separation and Gas Transport

Selective conversion of two waste carbon resources—polyethylene and CO 2 —into valuable chemicals through tandem catalysis offers a promising way to recover resources. However, current systems often have low selectivity for light aromatics in the liquid products, leading to mixtures of linear and cyclic compounds that are hard to separate. In this study, we developed a one-step process using an oxide–zeolite catalyst (CuFeO 2 + Ga-[Ga]/Zeolite Socony Mobil (ZSM)-5) at 400 °C and atmospheric pressure to produce separable liquid aromatics and CO from polyethylene and CO 2 at the same time. The synergistic effect between cationic Ga species and Brønsted acid sites in Ga-[Ga]/ZSM-5 promotes dehydrogenation while reducing typical hydrogen-transfer reactions, resulting in significant H 2 production. Meanwhile, the CuFeO 2 component supports the reverse water–gas shift reaction, shifting the reaction equilibrium and increasing the formation of aromatics through better hydrogen utilization. This cascade catalytic system achieves 99% selectivity toward separable aromatics in the liquid products and 91.9% toward C 1 –C 2 aliphatic hydrocarbons in the gaseous products. The yield of aromatics reaches 75.3 weight percent (wt%), with benzene, toluene, and xylene making up 81.1% of this fraction. Additionally, CO 2 conversion reaches up to 10.9 mmol per gram of polyethylene. This strategy effectively turns waste plastics and CO 2 into valuable products, offering a practical approach for was...