Giant electrostrain coefficient under low driving electric field in sodium potassium niobate piezoelectric ceramics with symmetrical bipolar strain

作者：Fuzhi Cao, Zhenyong Cen, Ze Xu, Xin Zhang, Xiaoming Shi, Houbing Huang, Zhaobo Liu, Yixuan Liu, Xianxian Cai, Dong Mei Zhu, Ke Wang, Zhongshang Dou, Chaofeng Wu, Nengneng Luo · 发表于：Nature Communications · 年份：2025 · DOI：10.1038/s41467-025-65521-5 · 被引用次数：5 · 研究领域：Ferroelectric and Piezoelectric Materials、Dielectric materials and actuators、Advanced Sensor and Energy Harvesting Materials

Currently, achieving highly symmetrical bipolar strain and high electrostrain under low driving electric field remains challenging in piezoelectric materials. The designed potassium sodium niobate-based ceramics exhibit highly symmetrical bipolar strain and ultrahigh electrostrain coefficient (~2000 pm/V) under a low driving electric field of 8.4 kV/cm through A-site defect engineering and charge compensation. The highly symmetrical bipolar strain is related strongly to the lowly aligned defect dipoles by partially substituting A-site (Na+/K+) ions with Mn2+. The eye-catching performance is ascribed to the unique microstructure of atomic-scale polar nanoregions embedded in nano-domains (~34 nm) by tuning Na+/K+ ions deficiency and coexistence of multiple phases. Phase-field simulations reveal that flattened energy barrier and multiphase nanodomains interplay to boost electrostrain at low driving fields. This work provides an innovative way of designing lead-free piezoelectric materials with highly symmetrical bipolar strain and giant electrostrain coefficient at low driving electric field, promising for high-precision actuators applications. The authors design potassium sodium niobate-based ceramics exhibiting highly symmetrical bipolar strain and high electrostrain coefficient (~2000 pm/V) under a low driving electric field of 8.4 kV/cm through A-site defect engineering and charge compensation.