Fully Reversible Photoelectronic Switching Enabled by Delocalized Excitons in a Single Superatom Junction

作者：Wei Pei, Pingping Han, Si Zhou, Xueke Yu, Jijun Zhao · 发表于：Journal of the American Chemical Society · 年份：2025 · DOI：10.1021/jacs.5c19434 · 被引用次数：5 · 研究领域：Molecular Junctions and Nanostructures、Nanocluster Synthesis and Applications、Magnetism in coordination complexes

Single-molecule switches, the smallest fundamental components of nearly all electronic devices, represent an essential pathway toward device miniaturization and multifunctionality. However, achieving fully reversible, robust, and atomically precise photoelectronic switching remains a grand challenge. Herein, we introduce a class of gate-controlled and reversible single-cluster photoelectronic switches based on ligand-protected M@Au 12 (M is a heteroatom dopant) superatoms. The electronic coupling between the dopant atom and the Au 12 cage leads to distinct superatomic configurations, which modulate the energy barrier for electron transfer upon photoexcitation. The superatomic clusters with a valence electron count of 18 exhibit strong excitonic delocalization that induces a large dipole moment. When covalently anchored between gold electrodes via halide linkers, the single-cluster junction enables fully reversible photoconductive behavior with contact-resistance ratios of 10 4 –10 5 between dark and illuminated states under a low gate voltage (0.50 V). These results provide vital insights into the design of molecular switches with low power consumption, ultrafast response, and high on/off ratios, paving the way for atomic-scale manufacturing.