Precise synthesis of telechelic rodlike polyisocyanides: versatile building blocks for fabricating polymer frameworks with controllable pore-apertures

作者：Yang Zong, Run‐Tan Gao, Na Liu, Shixing Lei, Zhan‐Ting Li, Zong‐Quan Wu · 发表于：Chemical Science · 年份：2025 · DOI：10.1039/d5sc07130e · 被引用次数：4 · 研究领域：Covalent Organic Framework Applications、Synthesis and Properties of Aromatic Compounds、Advanced Polymer Synthesis and Characterization

Bis(phenylethynyl)palladium catalysts initiate living polymerization of various isocyanides. The resulting polyisocyanides serve as building blocks for the fabrication of covalent polymer frameworks with customizable pore structures.