Cis -difluoromethyl hetarylative dearomatization by a radical docking-migration cascade

作者：Jie Wang, Hao Kang, Shan Yang, Zhu Cao, Xiangyang Chen, Chen Zhu · 发表于：Chemical Science · 年份：2025 · DOI：10.1039/d5sc07904g · 被引用次数：3 · 研究领域：Radical Photochemical Reactions、Catalytic C–H Functionalization Methods、Oxidative Organic Chemistry Reactions

We report the first example of an uncyclized cis -selective dearomatization reaction using a radical docking-migration strategy. The reaction proceeds readily under photochemical conditions without the use of extra photosensitizers.