Stiffening Organic Crystals through Polymerization Using Visible Light

作者：Linfeng Lan, Yuxing Zhou, Liang Li, Chenguang Wang, Pancě Naumov, Hongyu Zhang · 发表于：Journal of the American Chemical Society · 年份：2025 · DOI：10.1021/jacs.5c15122 · 被引用次数：11 · 研究领域：Photochromic and Fluorescence Chemistry、Polydiacetylene-based materials and applications、Luminescence and Fluorescent Materials

High Resolution Image Download MS PowerPoint Slide Soft organic crystals that combine high strength and toughness are essential for flexible electronics and bioinspired devices, but they often compromise one property for the other. Here, we demonstrate a visible-light–driven, single-crystal-to-single-crystal photopolymerization of 1,1′-dioxo-1 H,1′ H -[2,2′-biindene]-3,3′-diyl-bis(decanoate) ( B10 ) into a polymeric crystal ( PB10 ) that simultaneously with polymerization enhances its mechanical strength and toughness. Under white-light irradiation (2.5 W cm –2 ), centimeter-long B10 needles exhibit splitting, coiling, and straightening, accompanied by a color change from red to colorless. This transformation is accompanied by a molecular reorganization, where the weak (π···π stacking) interactions are replaced by stronger (C–C) bonds, resulting in a drastic change in mechanical properties. As a result, upon photopolymerization, the PB10 crystals transition from purely elastic to elastic/plastic, with a nearly 228-fold increase in toughness. This polymerization is also accompanied by increases in tensile modulus and a nearly 81-fold increase in tensile toughness. Remarkably, the PB10 crystals exhibit a load-bearing capacity exceeding 1 × 10 5 times their own mass, additionally reflecting the dramatic enhancement in mechanical strength.