Four-Component Reaction of Sodium Nitrite, Aromatic Alkenes, P 4 S 10 , and Alcohols Leading to β-Oximino Phosphorodithioates

作者：Jian Huang, Runmei Li, Yufen Lv, Fei Jia, Huilan Yue, Zi Yang, Zuli Wang, Wei Wei, Dong Yi · 发表于：The Journal of Organic Chemistry · 年份：2025 · DOI：10.1021/acs.joc.5c02106 · 被引用次数：16 · 研究领域：Synthesis and Characterization of Heterocyclic Compounds、Synthesis of heterocyclic compounds、Sulfur-Based Synthesis Techniques

A simple and efficient strategy has been developed to access β-oximino phosphorodithioate through additive-free four-component reactions of sodium nitrite, aromatic alkenes, P 4 S 10, and alcohols. The present reaction was carried out under mild conditions through a positive ion process. A series of β-oximino phosphorodithioates could be obtained in moderate to good yields by employing sodium nitrite as a promoter and an oxime source.