From Global Flexibility to Local Flexibility: Enable A–B Stacked Metal–Organic Framework for One‐Step Ethylene Purification from Complex Gas Mixtures

作者：Yanan Wang, Hao Wang, Huiyin Lin, Longsheng Yang, Fengqi Huang, Xing Liu, Hanting Xiong, Jingwen Chen, Zhenyu Zhou, Shixia Chen, Shuguang Deng, Jun Wang · 发表于：Angewandte Chemie International Edition · 年份：2025 · DOI：10.1002/anie.202516666 · 被引用次数：8 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Covalent Organic Framework Applications、Nanoplatforms for cancer theranostics

Abstract Flexible metal–organic framework (MOF) adsorbents can achieve exceptional separation performances under appropriate stimuli, especially for complex gas mixtures. However, their intrinsic global flexibility often leads to unsatisfactory separation selectivity, which hampers the practical applications. Herein, we propose a “rotor‐locker” strategy to convert an A–B stacked Cd‐MOF‐GF (GF = global flexibility) into Cd‐MOF‐LF (LF = local flexibility) for efficient one‐step C 2 H 4 separation from multiple complex gas mixtures. The grafted methyl groups serve as lockers to suppress global flexibility while preserving local stimulus‐responsive behavior. As a result, Cd‐MOF‐LF exhibits a 10‐fold increase in C 2 H 2 uptake (1.95 mmol g −1 ) compared to Cd‐MOF‐GF (0.19 mmol g −1 ) at 0.1 bar and 298 K, yielding a record selectivity of 9.2 for C 2 H 2 /C 2 H 4 (50/50) among similar adsorbents. Moreover, the selective capture of C 2 H 6 and CO 2 impurities is also significantly enhanced. Dynamic breakthrough experiments demonstrate that the Cd‐MOF‐LF column enables direct separation of polymer‐grade C 2 H 4 (>99.9%) with a high productivity of 0.79 mmol g −1 from a quaternary C 2 H 2 /C 2 H 6 /CO 2 /C 2 H 4 (1v/33v/33v/33v) gas mixture. Density functional theory calculations reveal a lower deformation energy (−3.99 kJ mol −1 ) and specific adsorption sites for Cd‐MOF‐LF.