Heterojunction-Coated Graphite Anode Enables Fast Charging via Built-In Electric Field-Regulated Interfacial Li-Ion Transport

作者：Yeliang Sheng, Xinyang Yue, Wei Hao, Luoyi Ding, Jiyi Zhu, Zheng Liang · 发表于：ACS Energy Letters · 年份：2025 · DOI：10.1021/acsenergylett.5c02653 · 被引用次数：11 · 研究领域：Advancements in Battery Materials、Advanced Battery Technologies Research、Advanced Battery Materials and Technologies

The sluggish Li-ion transport kinetics across anode interfaces remain a critical bottleneck limiting the fast-charging capability of lithium-ion batteries (LIBs). Herein, we design a lithiophilic Nb 2 O 5 /Zr 6 Nb 2 O 17 (N/ZN) heterojunction to regulate the Li-ion transport behavior across the graphite anode interface. The tailored work function difference between Nb 2 O 5 and Zr 6 Nb 2 O 17 components establishes an internal built-in electric field that synergistically addresses the challenges: (i) accelerating interfacial Li ion (Li + ) diffusion; (ii) optimizing Li intercalation/deintercalation kinetics; (iii) lowering the desolvation energy barrier. Therefore, the graphite anode with the N/ZN coating achieves 80.9% capacity retention at 6C-rate charging while effectively suppressing Li plating. This work demonstrates a heterojunction engineering strategy that concurrently enhances ionic transport and interfacial stability, offering a pathway for developing fast-charging anodes.