Two-Dimensional Dual-Switchable Ferroelectric Altermagnets: Altering Electrons and Magnons

作者：ShuaiYu Wang, Weiwei Wang, Jiaxuan Fan, Xiaodong Zhou, Xiaoping Li, Lei Wang · 发表于：Nano Letters · 年份：2025 · DOI：10.1021/acs.nanolett.5c03483 · 被引用次数：20 · 研究领域：Multiferroics and related materials、Ferroelectric and Piezoelectric Materials、Magnetic and transport properties of perovskites and related materials

We predict a new class of two-dimensional (2D) materials, termed dual-switchable ferroelectric altermagnets (FEAMs), where reversing the ferroelectric polarization simultaneously alters both electronic spin splitting and magnonic chirality splitting. This provides a pathway for the unified electrical manipulation of both ground-state electron spin textures and collective magnon excitations within a single monolayer, a largely unexplored area. Employing symmetry analysis and first-principles calculations on five candidates identified via database screening (exemplified by CrPS 3 and V 2 I 2 O 2 BrCl), we elucidate the mechanism in FEAMs. Ferroelectricity driven by specific atomic displacements breaks inversion symmetry while preserving key spin group symmetries (e.g., [C 2 ||M]). This dual switch could be experimentally observed through a magneto-optical Kerr effect sign change. This work establishes a material-specific pathway toward integrating electrical control over coupled electronic and magnonic properties in two dimensions, paving the way for novel multifunctional spintronic and magnonic applications.