Boosting Zn2+ intercalation via high-entropy doping and dynamic electron reservoirs for high-performance Zn-Mn batteries

作者：Kaisheng Sun, Yanlei Geng, Liang Li, Shengen Gong, Zhiqi Chen, Fangfei Li, Xiaoteng Jia, Caiyun Wang, Danming Chao · 发表于：Acta Materialia · 年份：2025 · DOI：10.1016/j.actamat.2025.121549 · 被引用次数：2 · 研究领域：Advanced battery technologies research、Advanced Battery Materials and Technologies、Supercapacitor Materials and Fabrication

Among manganese oxides, MnO with the highest theoretical capacity holds promise for ultra-high energy density Zn-ion batteries but is restricted ion/electron migration. Here, we synthesized a carbon-coated, high-entropy-doped MnO and intermetallic compounds (IMC) heterostructure (HE-MnO/IMC) by integrating high-entropy doping and heterojunction strategies to address intrinsic challenges. Carbon coating with abundant C = O bonds externally provides a rapid transport pathway for Zn 2+ . High-entropy doped MnO internally optimizes Zn 2+ migration via lattice distortion, while IMC optimizes electron transfer through interfacial effects and maintains charge balance as a dynamic electron reservoir. This integrated design strategy of complex structures and synergistic effects facilitates efficient ion and electron transport, achieving excellent rate performance (136.4 mAh g -1 at 5.0 A g -1 ) and stability (90.9% retention after 10,000 cycles). This work provides a new paradigm for the precise regulation of the reactive kinetic behaviour of functional materials. High-entropy doping and heterojunction spatial coupling via one-step heat treatment overcome ion/electron transport limitations in conventional MnO-based Zn 2+ storage.