Recent Progress in Electrochemical CN Coupling Reactions

作者：Chu Zhang, Chunyuan Feng, Lixiang Zhong, Chade Lv · 年份：2025 · DOI：10.1002/9783527849291.ch13 · 被引用次数：7 · 研究领域：CO2 Reduction Techniques and Catalysts、Ammonia Synthesis and Nitrogen Reduction、Radical Photochemical Reactions

Electrocatalytic through C  N coupling with CO 2 and nitrogen-containing species (N 2 , NO, NO 2 − and NO 3 − , etc.), as a “green synthesis strategy”, not only effectively reduces the environmental pollution problems, but also establishes a new route for the synthesis of value-added chemicals, including urea, amide and other high value-added organic nitrogen-containing products. This chapter summarizes the development history of electrocatalytic C  N coupling reactions and basic concept systematically. In addition, this chapter mainly emphasizes the research progress in the electrocatalysts exploration, the reaction mechanism of C  N coupling, as well as the advanced in situ characterization techniques. This chapter aims at promoting the overall understanding in this field and paving the way for synthesis other important chemicals through electrocatalytic C  N coupling under mild conditions.