Steering CO 2 Electroreduction Pathway via Tuning Microenvironment of Cobalt Center in Molecular Catalysts

作者：Mingjie Wu, Siyi Yang, Yang Gao, Zhangsen Chen, Fang Dong, Huiyu Lei, Yingkui Yang, Ning Chen, Sasha Omanovic, Tom Regier, Xun Cui, Bao Yu Xia, Gaixia Zhang, Shuhui Sun · 发表于：ACS Nano · 年份：2025 · DOI：10.1021/acsnano.5c09554 · 被引用次数：8 · 研究领域：CO2 Reduction Techniques and Catalysts、Electrocatalysts for Energy Conversion、Ionic liquids properties and applications

Owing to its chemical stability and molecular-level structural tunability, the molecular electrocatalyst cobalt phthalocyanine (CoPc) demonstrates significant potential for the electrochemical reduction of CO 2 (CO 2 RR). However, the specific catalytic reaction process of CO 2 RR and the dynamic structural evolution mechanisms of CoPc remain a contentious subject. Elucidating the reaction pathways of CO 2 electroreduction to CO and tracking structural evolution pose substantial challenges. In this study, we first used density functional theory (DFT) calculations to reveal the sequential proton–electron transfer (SPET) mechanisms for CO 2 RR on CoPc. Moreover, in situ X-ray absorption spectroscopy (XAS) elucidated a detailed deactivation mechanism, providing insights into the transition from single atomic sites (SAs) to nitrogen-coordinated nanoclusters (NCs) during CO 2 reduction. Based on these insights, we modified the pendant groups by introducing electron-withdrawing fluorine groups to change the reaction pathways of [*-COOH] 2– to the concerted proton–electron transfer (CPET) process, thereby effectively promoting the CO 2 electroreduction to CO. The presence of electron-withdrawing fluorine groups triggers central electron delocalization within CoPc, effectively mitigating the demetalation effect and enhancing the electron donation ability of Co active sites. As a result, we observed a markedly enhanced CO 2 RR performance, exhibiting high stability, activity, and FE C...