Unveiling the Reaction Mechanism of Selective Catalytic Reduction of NO with NH 3 over Active Mn–W Dinuclear Sites

作者：Meng Gao, Gao Qing Lu, Zhuocan Li, Xin Wang, Rucheng Duan, Yu Fu, Guangzhi He, Hong He · 发表于：Environmental Science & Technology · 年份：2025 · DOI：10.1021/acs.est.5c06059 · 被引用次数：15 · 研究领域：Catalytic Processes in Materials Science、Ammonia Synthesis and Nitrogen Reduction、Nanomaterials for catalytic reactions

Mn-based oxide catalysts have promising potential in the selective catalytic reduction of NO with NH 3 (NH 3 -SCR) due to their excellent low-temperature activity. However, poor N 2 selectivity severely restricts their large-scale practical applications. In this study, we achieved an improvement in both activity and selectivity of Mn-based SCR catalysts by W modification and revealed the mechanism by which the formation of Mn–W dinuclear active sites enhances their performance. By combining experimental measurements and density functional theory (DFT) calculations, the improved NH 3 -SCR performance of the MnW/TiO 2 catalyst was attributed to the significant redox role of W, resulting from the formation of strongly interacting Mn–W dinuclear sites. The entire NH 3 -SCR reaction pathway over the Mn–W dinuclear site was elucidated at the atomic level, confirming that the W sites played a redox role in the reaction, specifically by directly participating in the oxidative activation of NH 3 . This work elucidates the working principle of dinuclear active sites in the NH 3 -SCR reaction and provides valuable insight for the development of future generation high-performance SCR catalysts.