Construction of Atomically Dispersed Ni on Tensile‐Strained TiO 2 for Enhanced Photocatalytic Reduction of CO 2 to HCOOH

作者：Shoucan Ren, Huimin Hao, Yichen Fan, Jiaming Li, Fei Tian, Jian Liu, Changchao Jia · 发表于：Advanced Functional Materials · 年份：2025 · DOI：10.1002/adfm.202515558 · 被引用次数：17 · 研究领域：Advanced Photocatalysis Techniques、Catalytic Processes in Materials Science、CO2 Reduction Techniques and Catalysts

Abstract Solar‐driven photocatalytic CO 2 reduction offers a promising pathway for sustainable fuel production; however, its efficiency is hindered by rapid carrier recombination and slow surface reaction kinetics. In this study, tensile‐strained Ni/TiO 2 catalysts are synthesized via the in situ topological transformation of bimetallic metal–organic frameworks (MOFs). By modulating the ethylene glycol/water solvent ratios (a 3:1 volume ratio achieving 3% lattice expansion), precise control over strain levels is achieved. Advanced characterization confirms the incorporation of atomically dispersed penta‐coordinate Ni species into TiO 2 lattices. The induced strain not only facilitates the efficient separation and migration of photogenerated carriers but also enhances CO 2 adsorption capacity, resulting in a significant HCOOH yield of 140.0 µmol g −1 h −1 for Ni/TiO 2 ‐EG45, which is ≈5 times higher than that of low‐strain counterparts. Furthermore, introducing H 2 O 2 promotes proton‐coupled electron transfer, thereby further enhancing both the yield (242.7 µmol g −1 h −1 ) and selectivity (≈100%) of HCOOH production. This strain engineering approach provides novel insights into microenvironment regulation for designing highly efficient photocatalytic systems.