Tailoring CuO x Films via Open‐Air Spatial Atomic Layer Deposition and Their Application in Room‐Temperature Humidity Sensing

作者：A.M. Shahin, Agosh Saini, Na Young Kim, Kevin P. Musselman · 发表于：Small · 年份：2025 · DOI：10.1002/smll.202506835 · 被引用次数：2 · 研究领域：Copper-based nanomaterials and applications、ZnO doping and properties、Electronic and Structural Properties of Oxides

Abstract This study demonstrates the tunability of copper oxide (CuO x ) thin films synthesized using open‐air atmospheric‐pressure spatial atomic layer deposition (AP‐SALD). By systematically varying the deposition temperature and copper precursor flow rate, as well as introducing nitrogen doping through in situ oxidant switching (from H 2 O to ammonium hydroxide (NH 4 OH)), the crystallinity, oxidation state, chemical composition, carrier concentration, and resistivity of CuO x films are modulated. Under optimized conditions, CuO x films achieve a very low resistivity of 0.178 Ω·cm and a high carrier concentration of 10 19 cm − 3 —among the best reported for AP‐SALD‐deposited CuO x . As proof of properties tailoring, these films are integrated into interdigitated‐electrode devices and evaluated as chemiresistive humidity sensors at room temperature. While CuO x films cannot typically sense humidity at room temperature, a film deposited at 225 °C and 350 sccm Cu flow exhibits a limit of detection of 99 ppm and a sensitivity of 0.244 Ω ppm −1 . This work establishes AP‐SALD as a powerful tool for tuning CuO x film properties via controlled deposition conditions and in situ doping—enabling application‐specific optimization for future optoelectronic or sensing platforms.