Tailoring photocatalytic activity in porphyrin-MOFs: the role of amino-functionalized pillars in CO 2 adsorption and band structure modulation

作者：Xing-Zhe Guo, Chi L. Cao, Wei Liu, Weiwei Xu, Nan Ma, Xiaoxia Zhang, Jinfa Chang, Zihao Xing · 发表于：Journal of Materials Chemistry A · 年份：2025 · DOI：10.1039/d5ta03720d · 被引用次数：7 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Gas Sensing Nanomaterials and Sensors、Carbon Dioxide Capture Technologies

Porphyrin-based pillared MOFs were synthesized via an amino-functionalization strategy, which enhanced CO 2 adsorption, light absorption and charge separation resulting in superior photocatalytic CO 2 reduction performance.