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Triazine-cored donor–acceptor covalent organic framework promotes highly efficient photocatalytic synthesis of H 2 O 2

作者:Lihua Li, Xin Yao, Weizhi Ou, Jing Chai, Ru Ma, Chenglong Ran, Anzhi Ma, Xiaojun Shi, Pifeng Wei, Hong Dong, Hongpeng Zhou, Wen-Bing Yang, Hai‐Yu Hu, Jianfeng Wu, Hui Peng, Guofu Ma · 发表于:Green Chemistry · 年份:2025 · DOI:10.1039/d5gc01754h · 被引用次数:29 · 研究领域:Advanced Photocatalysis Techniques、Covalent Organic Framework Applications、Caching and Content Delivery

A D–A COF (TPB–TPT-COF) with triazine groups enabled photocatalytic H 2 O 2 production at 6740 μmol g −1 h −1 without sacrificial agents. DFT and experiments show its D–A structure boosts carrier separation and transport for enhanced performance.