Photocatalytic cleavage of unactivated C(sp 3 )–H bonds via the uranyl cation: enabling the allylation of alkanes

作者：Yanxin Jiang, Song-Bai Tang, Y Z Luo, Zixin Wang, Zekai Li, Jing Su · 发表于：Organic Chemistry Frontiers · 年份：2025 · DOI：10.1039/d5qo00649j · 被引用次数：5 · 研究领域：Catalytic C–H Functionalization Methods、Radical Photochemical Reactions、Chemical Reactions and Isotopes

The uranyl cation serves as a highly efficient direct hydrogen atom transfer ( d -HAT) catalyst, enabling direct allylation of C(sp 3 )–H bonds with broad substrate compatibility, scalability, and potential for diverse functionalization.