Temperature-Dependent Synthesis of Oxygen Vacancy-Rich NH 2 –UiO-66: A Strategy for Sustainable Photocatalytic Nitrogen Fixation

作者：Tianqi Shen, Xinya Feng, Linkun Fan, Lan Li, Yiming Zhang, Bo Chai, Usman Khan, Xusheng Wang · 发表于：Crystal Growth & Design · 年份：2025 · DOI：10.1021/acs.cgd.5c00418 · 被引用次数：17 · 研究领域：Ammonia Synthesis and Nitrogen Reduction、Advanced Photocatalysis Techniques、Metal-Organic Frameworks: Synthesis and Applications

Photocatalytic nitrogen fixation is a promising strategy for sustainable energy production, with efficient and cost-effective photocatalysts being crucial for its success. In this study, oxygen vacancy-rich photocatalysts (100-U, 200-U, and 300-U) were successfully synthesized via low-temperature calcination of NH 2 –UiO-66. Electron paramagnetic resonance analysis confirmed a significant increase in oxygen vacancies during calcination, enhancing active sites for photogenerated charge carrier capture. The bond length, thermogravimetric analysis, and X-ray diffraction revealed that calcination at 200 °C, compared to other temperatures, led to the cleavage of C1–C2 bonds and the breakage of Zr–OH–Zr bonds, promoting oxygen vacancy formation while preserving structural integrity. Photocatalytic results showed that the 200-U sample exhibited the highest nitrogen fixation performance, with an NH 3 yield of 17.2 μmol g –1 h –1, approximately twice that of the original NH 2 –UiO-66. This work provides valuable insights into the partial decomposition process and oxygen vacancy formation mechanism, contributing to the design of photocatalysts with abundant oxygen vacancies.