Topological variety and self-sorting in homo- and heteroleptic Pd n L 2 n metallo-supramolecular assemblies

作者：Laura Neukirch, Guido H. Clever · 发表于：Chemical Science · 年份：2025 · DOI：10.1039/d5sc03203b · 被引用次数：34 · 研究领域：Supramolecular Chemistry and Complexes、Supramolecular Self-Assembly in Materials、Metal-Organic Frameworks: Synthesis and Applications

= 2-8) architectures that has so far been found experimentally. We next discuss strategies for increasing the structural complexity even further through the non-statistical self-assembly of heteroleptic cages, the orientational self-sorting of asymmetric ligands, and chiral self-sorting effects. Special emphasis will be placed on factors governing the particular self-assembly outcome as well as on rationalization approaches based on computations or geometrical considerations.