The Effect of Adding Different Elements (Mg, Fe, Cu, and Ce) on the Properties of NiCo2OX for CO-Catalyzed Oxidation

作者：Jiefeng Wang, Zhili Chen, Tianqi Cao, Junsheng Yang, Yijian Kuang, Jiangang Kang · 发表于：Materials · 年份：2025 · DOI：10.3390/ma18112554 · 被引用次数：4 · 研究领域：Catalytic Processes in Materials Science、Catalysis and Oxidation Reactions、Electrocatalysts for Energy Conversion

In this experiment, NiCo2Ox catalysts, with different elements added (Mg, Fe, Cu, and Ce), were prepared using the co-precipitation method to investigate their catalytic performance for carbon monoxide, as well as their water resistance and sulfur resistance. Combined with the sintering flue gas environment of Baosteel Zhanjiang Iron and Steel Co., Ltd., it provides a reference for the catalytic oxidation of CO in complex environments. The results reveal that the Fe-added catalysts exhibited a better CO catalytic performance and possessed good redox properties, and the Fe metal ion-added NiCo2Ox catalysts showed a CO catalytic efficiency of 91.72% at 100 °C. Meanwhile, the Fe-added catalysts had the strongest resistance to water, with a conversion of 98.37% to CO at 140 °C, and with 10% water vapor. The Ce-added catalyst showed a better SO2 resistance and hybrid resistance of SO2 and H2O. Under the condition of sulfur addition, the CO conversion of the Ce-added catalyst was as high as 63.07% after 4 h of SO2 introduction, and the efficiency could be restored to 100% after cutting off the supply of SO2. Under the conditions of sulfur addition and water addition, the CO conversion of the catalyst was 98.23% after cutting off the SO2.