Morphology-Controllable Liquid Metal/Diamond Sandwich-Structured Thermal Interface Material toward High-Efficiency Thermal Management

作者：Xingye Wang, Yandong Wang, Boren Yang, Yingying Guo, Kang Xu, Zhenbang Zhang, Rongjie Yang, Jianxiang Zhang, Boda Zhu, Yue Qin, Yiwei Zhou, Linhong Li, Maohua Li, Tao Cai, Kazuhito Nishimura, Cheng‐Te Lin, Nan Jiang, Wen Dai, Jinhong Yu · 发表于：ACS Nano · 年份：2025 · DOI：10.1021/acsnano.5c03918 · 被引用次数：53 · 研究领域：Thermal properties of materials、Heat Transfer and Optimization、Composite Material Mechanics

With the exponential growth of AI computing power, the power density of electronic devices has exceeded 1 kW/cm 2, rendering traditional thermal management materials insufficient to handle the challenges of high heat flux density. Developing thermal interface materials (TIMs) with both high thermal conductivity (≥10 W m –1 K –1 ) and interface compatibility is crucial. This study introduces a dual-level interface engineering strategy, constructing a thermally conductive adhesive layer with low interfacial thermal resistance (4 K mm 2 W –1 ) and excellent electrical insulation properties (2.25 × 10 13 Ω cm) through the incorporation of liquid metal (LM) microspheres (average particle size: 6.4 μm) and micron-sized diamond blending. By combining shear-induced in situ formation of a nanoscale gallium oxide interfacial layer with gradient rotational speed control, a three-dimensional continuous thermal conductive network composite material was successfully fabricated, achieving an ultrahigh thermal conductivity of 237.9 W m –1 K –1 . The “sandwich” packaging structure effectively mitigates the risk of LM leakage. When applied to high-power devices, the surface temperature of the heat source decreases by up to 69% compared to without TIMs. Further development of the through-plane heat transfer and in-plane waste heat conversion device allows the conversion of waste heat into a stable voltage output of 7.35 V. This marks the successful transition of TIMs from heat dissipation to en...