Site-selective ligand defects open up a Zr-oxo cluster electron transfer pathway for CO 2 photoreduction

作者：Yuhang Qi, Yiqiang He, Yuxin Liu, Zhe Zhang, Chunguang Li, Fanchao Meng, Shiyu Wang, Xiaobo Chen, Zhan Shi, Shouhua Feng · 发表于：Chemical Science · 年份：2025 · DOI：10.1039/d5sc01194a · 被引用次数：12 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Advanced Photocatalysis Techniques、Nanocluster Synthesis and Applications

-Zr pathways, effectively narrowing the band gap and suppressing photoinduced charge recombination. These findings are expected to provide alternative perspectives on selective defect engineering for the design and manufacture of high-performance MOF photo-catalysts for a variety of value-added engineering applications.