Optical spectroscopy of defects in atomically thin transition metal dichalcogenides

作者：Frederico B. Sousa, Kazunori Fujisawa, Felipe Menescal, Matheus J. S. Matos, M. A. Pimenta, Hélio Chacham, Mauricio Terrones, Leandro M. Malard, Bruno R. Carvalho · 发表于：Applied Physics Reviews · 年份：2025 · DOI：10.1063/5.0251288 · 被引用次数：16 · 研究领域：2D Materials and Applications、Perovskite Materials and Applications、Chalcogenide Semiconductor Thin Films

In this review, we address the optical signatures of defects in two-dimensional transition metal dichalcogenides (2D TMDs), whether they occur unintentionally during growth or are deliberately introduced post-growth. We detail their primary responses as probed by photoluminescence (PL), magneto-PL, Raman, tip-enhanced PL and Raman, and nonlinear spectroscopies. Defects significantly impact the electronic, vibrational, magneto-optical, and nonlinear properties of TMDs, influencing outcomes based on application needs. This comprehensive overview highlights the distinctive optical fingerprints of various defects, providing guidance for their identification and characterization. Additionally, we discuss new optical phenomena induced by defects in TMD monolayers and future challenges in defect engineering for these materials. The insights from this review underscore the potential of TMDs for technological applications, with advancements in spectroscopy and defect engineering driving future innovations and enhancing our understanding of these materials.