Conversion of CO 2 into cyclic carbonates using an ionic porous organic cage

作者：Qianqian Mao, Jinjin Zhang, Ming Liu · 发表于：Chemical Communications · 年份：2025 · DOI：10.1039/d5cc01691f · 被引用次数：13 · 研究领域：Carbon dioxide utilization in catalysis、CO2 Reduction Techniques and Catalysts、Ionic liquids properties and applications

and epoxides, generating cyclic carbonates in high yields. This POC catalyst is highly efficient, achieving a maximum yield of up to 90% with a turnover number (TON) of 3000 without requiring reaction solvents. Moreover, with the synergistic effect of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), the catalytic performance can be further enhanced across a wide substrate range.