Inside Front Cover: Indole‐Quinoline Transmutation Enabled by Formal Rhodium‐Carbynoid (Angew. Chem. Int. Ed. 25/2025)

作者：Lujie Liu, Meng‐Yang Tian, Zhi‐Yu Lang, Yongli Wang, Chun‐Yang He, Yong‐Zheng Chen, Wen‐Yong Han · 发表于：Angewandte Chemie International Edition · 年份：2025 · DOI：10.1002/anie.202510007 · 被引用次数：1 · 研究领域：Asymmetric Hydrogenation and Catalysis、Catalytic Cross-Coupling Reactions、Organometallic Complex Synthesis and Catalysis

Skeletal editing can rapidly forge valuable derivatives from parent molecule by late-stage simple transformations. In their Communication (e202501966), Wen-Yong Han et al. developed a Rh2(esp)2-catalyzed indole-quinoline transmutation using an α-diazotrifluoroethyl sulfonium salt, wherein the formal trifluoromethyl Rh-carbynoid (CF3C+ = Rh), a trifluoromethyl cationic carbyne (CF3C+:) equivalent, was involved.