A photo-Fenton-like (trideutero)methylation reaction of N/O heterocycles with DMSO(- d 6 ) induced by EDA complex photocatalysis

作者：Changsheng Qin, Chenxu Li, Fang Gao, Jingfang Wang, Zhihua Zhang, Shuai Zhang, Xinyue Li, Sun Yi, Meiqian Hu, Shoucai Wang, Fanghua Ji, Guangbin Jiang · 发表于：Green Chemistry · 年份：2025 · DOI：10.1039/d4gc05939e · 被引用次数：21 · 研究领域：Radical Photochemical Reactions、Fluorine in Organic Chemistry

We have achieved the (deutero)methylation of N/O heterocycles through a visible-light catalyzed strategy. This reaction employs DMSO(- d 6 ) as the methyl source and relies on the in situ generation of an active catalyst.