State‐of‐the‐Art, Insights, and Perspectives for MOFs‐Nanocomposites and MOF‐Derived (Nano)Materials

作者：Stefanos Mourdikoudis, Subhajit Dutta, Saqib Kamal, Sergio Gómez‐Graña, Isabel Pastoriza‐Santos, Stefan Wuttke, Lakshminarayana Polavarapu · 发表于：Advanced Materials · 年份：2025 · DOI：10.1002/adma.202415399 · 被引用次数：144 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、MXene and MAX Phase Materials、Advanced Photocatalysis Techniques

Abstract Composite structures created from metal‒organic framework (MOF) matrices are reviewed in this work. Depending on the nature of the second component apart from the MOF platform, several synergistic properties may arise; at the same time, the initial features of the single constituent materials are usually maintained, and individual shortcomings are mitigated. Currently, timely energy and environmental challenges necessitate the quest for more advanced materials and technologies. Significant developments in MOF‐nanocomposites have enabled their application across a wide range of modern and traditional fields. This review demonstrates in an exhaustive and critical way a broad range of MOF‐based nanocomposites, namely, MOF/perovskite nanoparticles (NPs), MOF/metal (non‐iron) oxide NPs, MOF/Fe 3 O 4 NPs, MOF/metal chalcogenide NPs, MOF/metal NPs, and MOF/carbon‐based materials, as well as nanocomposites of MOFs with other semiconductor NPs. Key points related to the synthesis, characterization, and applications of these materials are provided. Depending on their configuration, the composites under discussion can be applied in domains such as photoelectrochemical sensing, antibiotic/dye degradation, optoelectronics, photovoltaics, catalysis, solar cells, supercapacitors, batteries, water remediation, and drug loading. Sometimes, MOFs can undergo certain processes (e.g. pyrolysis) and act as precursors for composite materials with appealing characteristics. Therefore, a spe...