Ligand effects enhancing low-temperature oxygen reduction kinetics in neutral conditions

作者：Yongjian Zhao, Murong Huang, Yongshuai Kang, Yong Fang, Tianyou Zhao, Hu Wang, Jimmy Ou, Jiajun Liu, Meixi Zhong, Tao Wang, Xianhu Sun, Chenyang Zhao, Dan Wang · 发表于：Energy & Environmental Science · 年份：2025 · DOI：10.1039/d5ee01407g · 被引用次数：20 · 研究领域：Electrocatalysts for Energy Conversion、Fuel Cells and Related Materials、Molecular Junctions and Nanostructures

The local PO microenvironment activates the adjacent C atom to modulate the oxygen adsorption through the Yeager model, thereby enhancing the ORR kinetics even in hostile environments with low temperatures and proton concentrations.