A novel deep eutectic solvents as electrolyte for lithium-ion batteries and its electrochemical performance

作者：Chenhao Zhang, Jiaqi He, Yunjie Bao, Bin Han, Yuxia Liu, Dianchun Ju, Chun‐Yu Chen · 发表于：Chemical Physics Letters · 年份：2025 · DOI：10.1016/j.cplett.2025.142088 · 被引用次数：6 · 研究领域：Advancements in Battery Materials、Ionic liquids properties and applications、Extraction and Separation Processes

The carbonate-based organic electrolytes suffer from issues like flammability and degradation over extended cycling, which hinder the development of lithium-ion batteries. In this study, a lithium bis(trifluoromethanesulfonyl)imide– N , N ′-dimethylpropionamide(LiTFSI-DMPA) deep eutectic solvent(DES) was developed and applied as an electrolyte for lithium-ion batteries. The results indicate that the interaction between LiTFSI and DMPA enhances Li + transport, while the synergistic effects of multiple functional groups in DMPA and LiTFSI endow the electrolyte with good thermal stability . The assembled Li|LFP half-cell retained over 86.1 % of its capacity after 400 cycles at 1C, and exhibited superior rate performance compared to conventional carbonate-based organic electrolytes.