Magnetic Field-Enhanced Acidic CO 2 Electroreduction Reaction on Single Nickel-Site Catalysts

作者：Jia Song, Dayin He, Xianhui Ma, Peigen Liu, Wenxin Guo, Rongbo Sun, Feng Li, Zhicheng Zhong, Huang Zhou, Jun Tang, Jie Xu, Tongwei Wu, Lin Hu, Yuen Wu · 发表于：Journal of the American Chemical Society · 年份：2025 · DOI：10.1021/jacs.5c00858 · 被引用次数：48 · 研究领域：CO2 Reduction Techniques and Catalysts、Ionic liquids properties and applications、Catalysis and Oxidation Reactions

The synergistic integration of electrochemical reactions with an external magnetic field offers a powerful strategy for enhancing reaction performance. Herein, we introduce a flexible and continuously adjustable external magnetic field to enhance acidic CO 2 reduction reaction (CO 2 RR) performance. In an acidic electrolyte (pH = 0.91), the initial Faradaic efficiency (FE) of the CO 2 RR for CO is only 18%, which can be increased to 63.2% when a 2 T magnetic field is applied. More importantly, the introduction of this external magnetic field enables the continuous switching of CO 2 reduction products in a noncontact magnetic switching mode. Theoretical calculations demonstrate that the application of a magnetic field promotes CO 2 adsorption at Ni sites and inhibits the hydrogen evolution reaction (HER), ultimately enhancing CO 2 RR activity and selectivity. This work provides fresh insight into how an external magnetic field promotes CO 2 RR performance.