Enhancing the hydrogen evolution activity of diiron molecular electrocatalysts by modulating the substituent effect of carbon nanotubes

作者：Pei‐Hua Zhao, Shaojie Wang, Fan-Zeng Wei, Xue Su, Hui Gao · 发表于：Dalton Transactions · 年份：2025 · DOI：10.1039/d5dt00138b · 被引用次数：7 · 研究领域：Electrocatalysts for Energy Conversion、Metalloenzymes and iron-sulfur proteins、Advanced battery technologies research

. In contrast, the CNT-O-ADT hybrid, due to its electron-withdrawing alkoxy side chain, reduces the electron density of the catalytic center, resulting in the poorest HER performance. Overall, this activity modulation using different side-chain substituents holds great significance for the development and design of metal molecular catalysts.