The role of structural defects in the fluoride-mediated synthesis of aluminosilicate zeolites

作者：K. Christian Kemp, Ömer Faruk Altundal, Donghui Jo, Weidong Huang, Qiang Wang, Feng Deng, Germán Sastre, Suk Bong Hong · 发表于：Chemical Science · 年份：2025 · DOI：10.1039/d5sc00899a · 被引用次数：6 · 研究领域：Zeolite Catalysis and Synthesis、Mesoporous Materials and Catalysis

Defect microstructure type and quantity play a structure-directing role in synthesis of aluminosilicate zeolites under fluoride conditions. Defect formation is entropic in nature due to limited mobility of framework Al atoms and encapsulated F − ions.