Flat-Shaped Copper Nanoclusters with Near-Infrared Absorption for Enhanced Photothermal Conversion

作者：Bingzheng Yan, Jing Sun, Jiahe Liu, Lei Li, Hongwen Deng, Qinghua Xu, Song Wang, Hui Shen · 发表于：JACS Au · 年份：2025 · DOI：10.1021/jacsau.5c00099 · 被引用次数：19 · 研究领域：Nanocluster Synthesis and Applications、Gold and Silver Nanoparticles Synthesis and Applications、Advanced Nanomaterials in Catalysis

High Resolution Image Download MS PowerPoint Slide Atomically precise metal nanoclusters have emerged as a prominent area of research in recent years, yet the majority of previous studies have primarily concentrated on gold and silver ones. The challenge of controlling the shape of copper nanoclusters in order to investigate their relationship to properties remains a significant concern in contemporary scientific research. In this study, we successfully achieved shape control of a copper nanocluster with a rare flat oblate structure using a combination of multiple ligands (trifluoroacetic acid, 4-fluorothiophenol, and triphenylphosphine). The resulting nanocluster, with the composition Cu 62 (4-F-PhS) 30 (CF 3 COO) 8 (PPh 3 ) 6 H 10, features a flat metal core of aspect ratio as high as 2.6, which is stabilized by ligands attached to or bridged onto the flat kernel. Unlike most previously reported copper nanoclusters, Cu 62 exhibits absorption in the near-infrared range. Density functional theory calculations reveal that the main occurrence of near-infrared transitions takes place at the equatorial radius of the Cu 62 nanocluster metal core, corresponding to the radial exciton oscillation caused by the confinement of a flattened inner core structure, similar to the plasmon resonance in metal nanoparticles. The unique flattened oblate structure of the nanocluster can also promote the photothermal conversion efficiency (PCE). The temperature of the cluster solution increases fr...