CF 3 SO 2 Na-promoted photocatalytic aerobic oxidation of benzyl alcohols to aromatic aldehydes and aromatic esters

作者：Yong Liu, Weixin Xiao, Yue Zhang, Lunyu Ou, Zhengyi Yi, Xiaobo Yang, Hua Fu · 发表于：Organic & Biomolecular Chemistry · 年份：2025 · DOI：10.1039/d5ob00169b · 被引用次数：4 · 研究领域：Chemical Synthesis and Reactions、Sulfur-Based Synthesis Techniques、Organic and Inorganic Chemical Reactions

formed pentacoordinate sulfide showed excellent photocatalytic efficiency, with photocatalytic aerobic oxidation of benzyl alcohols providing aromatic aldehydes in good yields; photocatalytic aerobic oxidation of benzyl alcohols in other aliphatic alcohols afforded aromatic esters in moderate to good yields. The method avoids the use of precious transition-metal complexes and elaborate organic dyes as photocatalysts.