Ni-catalyzed C(sp 3 )–C(sp 3 ) cross-coupling to access γ-carbonyl alkylboronates and alkylsilicons enabled by cyclopropanol-derived homoenolates

作者：Linfei Zhu, Yang Sun, Hui Wang · 发表于：Organic Chemistry Frontiers · 年份：2025 · DOI：10.1039/d5qo00320b · 被引用次数：5 · 研究领域：Catalytic Cross-Coupling Reactions、Catalytic C–H Functionalization Methods、Organoboron and organosilicon chemistry

A nickel-catalyzed C(sp 3 )–C(sp 3 ) ring-opening cross-coupling reaction of cyclopropanols with α-boryl and α-silyl electrophiles is presented, offering an efficient route to access γ-carbonyl alkylboronates and alkylsilicons under mild conditions.