Eight-electron copper-hydride nanoclusters: synthesis, structure, alloying chemistry and photoluminescence

作者：Jing Sun, Jiahe Liu, Hai‐Feng Su, Simin Li, Xiongkai Tang, Zhen‐Lang Xie, Zhen Xu, Wenya Jiang, Jianyu Wei, Xuekun Gong, Ayisha He, Song Wang, De‐en Jiang, Nanfeng Zheng, Hui Shen · 发表于：Chemical Science · 年份：2025 · DOI：10.1039/d4sc08547g · 被引用次数：13 · 研究领域：Nanocluster Synthesis and Applications、Metal-Organic Frameworks: Synthesis and Applications、Inorganic Chemistry and Materials

clusters, which exhibit significant structural differences from the parent cluster. Both the homo and alloy clusters display dual-emission properties at 298 K, with the clusters additionally showcasing triple or even quadruple emission at 77 K. This work is anticipated to stimulate research interest in hydride-containing metal nanoclusters, focusing not only on compositional tailoring and structural engineering, but also on electronic structure details and potential applications.