Material characterization and engineering performance evaluation of phosphogypsum as a high-performance filler for bituminous pavements

作者：Xiong Xu, Guohao Xu, Xiaomei Huang, GM Badiul Alam, Xuyong Chen, Anand Sreeram · 发表于：Fuel · 年份：2025 · DOI：10.1016/j.fuel.2025.134977 · 被引用次数：13 · 研究领域：Innovative concrete reinforcement materials、Concrete and Cement Materials Research、Polymer Nanocomposites and Properties

The effective recycling of waste materials as alternatives to traditional mineral fillers in asphalt mixtures has both economic and environmental benefits. Phosphogypsum (PG), as one of the industrial solid wastes is a promising alternative to be used in asphalt mixture. However, in terms of the physical nature of PG, its high-absorption and moisture-expansion cause significant deterioration in engineering properties , particularly moisture-induced damage. To address these concerns, this study considered adopting polymeric diphenylmethane diisocyanate (PMDI) to activate asphalt binder with the introduction of active isocyanate (–NCO) groups, to chemically capture and stabilize the treated PG (TPG) fillers in the mixture. Based on this, the moisture-induced properties and other engineering performances of TPG-containing asphalt mixture (PGAM) with various PMDI contents were evaluated through a series of mechanical tests, and the chemical interaction mechanism between PG and PMDI in asphalt mixture was further simulated and analysed by X-ray diffraction (XRD), infrared spectroscopy (FTIR), thermogravimetry–differential thermogravimetry (TG-DTG), X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM) tests. The results indicated that PMDI can effectively improve the moisture-induced performance of PGAM, in addition to enhancing the high- and low-temperature stability and reducing rutting and cracking risks. The thermal and microstructural analyses confirm...