Preparation, microstructure and properties of C/Ta4HfC5-SiC composite fabricated by PIP method based on a new liquid precursor

作者：Fan Wan, Haolin Ma, Lin Zhang, Maofen He, Yurong Chen, Xuemei Li, Changqing Song, Junsheng Li · 发表于：Journal of the European Ceramic Society · 年份：2025 · DOI：10.1016/j.jeurceramsoc.2025.117281 · 被引用次数：5 · 研究领域：Advanced materials and composites、Advanced ceramic materials synthesis、Aluminum Alloys Composites Properties

A novel liquid Ta 4 HfC 5 precursor was produced by modified citric acid complexation method and C/Ta 4 HfC 5 -SiC composite was manufactured by precursor impregnation and pyrolysis (PIP) process. The powder obtained after 1800 ℃ heat treatment of the precursor has a diameter range of 50–300 nm, with a median diameter of ∼110 nm. The density and porosity of C/Ta 4 HfC 5 -SiC composite are 2.43 g/cm 3 and 13.2 %, respectively. Due to the toughening of fibers and the addition of SiC, the overall integrity of C/Ta 4 HfC 5 -SiC is improved, achieving high bending strength and fracture toughness of 392.6 MPa and 10.4 MPa·m 1/2 , respectively. After oxyacetylene ablation assessment of 60 s, the measured mass ablation rate and linear ablation rate of the composite were 11.6 mg/s and 9.1 µm/s, respectively. A complete oxide layer based on the joint effort of oxides of Ta(Hf) and Si was formed on the surface of the composite, with no exposed fibers observed.