Efficient Proton Conduction through [N···X···N] + Halogen Bond Coordination in Halogen‐Bonded Organic Frameworks

作者：Qi Zhao, Siyi Lin, Penghao Sun, Ya Lu, Qian Li, Zhen‐Nan Tian, Xuguan Bai, Jike Wang, Lu Wang, Shigui Chen · 发表于：Advanced Functional Materials · 年份：2025 · DOI：10.1002/adfm.202421755 · 被引用次数：20 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Covalent Organic Framework Applications、Fuel Cells and Related Materials

Abstract Advancing anhydrous proton‐conducting materials is essential for the fabrication of high‐temperature (>373 K) polymer electrolyte membrane fuel cells (HT‐PEMFCs) and remains a significant challenge. Herein, halogen‐bonded organic frameworks linked by [N···I··N] + interactions are reported as outstanding high‐temperature conductive materials. By incorporating carbazole groups into the monomers, two highly crystalline halogen‐bonded organic frameworks ( XOF‐CSP/CTP ) are constructed. These XOFs exhibit a high intrinsic conductivity (σ = 1.22 × 10 −3 S cm −1 ) under high‐temperature anhydrous conditions. Doping the XOFs with H 3 PO 4 allows the nitrogen sites and I + sites on the pore walls to stabilize and tightly confine the H 3 PO 4 network within the porous framework through hydrogen bonding, thereby enhancing proton conductivity under anhydrous conditions (σ = 1.02 × 10 −2 S cm −1 ). Temperature‐dependent curves and theoretical calculations indicate that proton transport is governed by a low‐energy barrier hopping mechanism. These materials exhibit excellent stability and maintain high proton conductivity across a broad temperature range. This work provides a new platform for designing anhydrous proton‐conducting materials with significant potential as high‐temperature proton exchange membranes.